凯斯特（尼古拉斯•凯奇 Nicolas Cage 饰）是一个恐怖分子，他本想杀死探员西恩（约翰•特拉沃塔 John Travolta 饰），却误杀了西恩的儿子，西恩更与凯斯特结下不共戴天之仇。在逮捕凯斯特归案之后，他以为可以划上句号，却得知凯斯特已经把一枚毒气炸弹投放在某个人群密集的角落。
为了查出炸弹地点，西恩决定利用整形手术，将昏迷中的凯斯特的脸换在自己身上，去假扮凯斯特身份套出他弟弟说出真相。这件事属于FBI高度机密，只有寥寥几人知情。
凯斯特醒来，此时他有着西恩的面相。于是他决定将计就计，将知情人杀掉之后，他就变成了西恩……
影片改编自尼克·托切斯的同名小说，讲述两个平行故事，分别围绕著名诗人但丁和他的代表作《神曲》展开：当代纽约，《神曲》原稿出现在一个黑市走私团伙的手中，厌倦现状的学者尼克（奥斯卡·伊萨克 Oscar Isaac 饰）被他们召唤去辨别真伪。尼克最终因诱惑而违抗黑手党偷走了手稿，和他的爱人茱丽叶塔（盖尔·加朵 Gal Gadot 饰）踏上了一条黑暗暴力之路，从隐喻式的地狱到天堂。 平行时空，但丁（奥斯卡·伊萨克 Oscar Isaac 饰）受困于和杰玛（盖尔·加朵 Gal Gadot 饰）的无爱婚姻，他逃到西西里岛创作了自己最伟大的作品《神曲》，使他逝去的爱人碧翠斯永垂不朽。 尼克和但丁的时间线编织不同的道路，但两人又紧密相连——都迷失在了在对爱、美和上帝预示的追逐中。
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